01 - Lightly grease a 9x9-inch baking pan and dust with a mixture of confectioners sugar and cornstarch, reserving the remainder for later use.
02 - Combine gelatin and 1/2 cup cold water in the bowl of a stand mixer. Let stand while preparing the syrup to allow the gelatin to bloom.
03 - In a medium saucepan, combine granulated sugar, corn syrup, 1/2 cup water, and salt. Stir over medium heat until sugar dissolves, then increase heat and bring to a boil without stirring. Heat to 240°F on a candy thermometer.
04 - With mixer on low speed, carefully pour hot syrup into bloomed gelatin. Gradually increase speed to high and beat for 10 to 12 minutes until thick, glossy, and tripled in volume. Add vanilla during the final minute of mixing.
05 - Quickly spread mixture evenly into prepared pan using a greased spatula. Smooth the top, then dust with more confectioners sugar and cornstarch mixture. Let set uncovered at room temperature for at least 4 hours, preferably overnight.
06 - Turn marshmallow slab onto a cutting board. Cut into 1-inch squares with a sharp knife or pizza cutter dusted in the sugar and cornstarch mixture. Toss each piece in remaining mixture to prevent sticking.